Core to Core Program
"Elements Function for Transformative Catalysis and Materials" 研究拠点形成事業 A.先端拠点形成型、革新的触媒・機能分子創製のための元素機能攻究

Publications

All Joint Publications Nagoya/Münster since 2008

2008

  1. “Solid-state 13C and 45Sc NMR studies on endohedral scandium-carbide metallofullerenes: a motional dynamics of Sc atoms in fullerenes”, H. Okinmoto, W. Hemme, Y. Ito, T. Sugai, R. Kitamura, H. Eckert, H. Shinohara, NANO 2008, 3, 21.
  2. “Heterolytic Cleavage of Dihydrogen by Frustrated Lewis Pairs Derived from α-(Dimesitylphosphino)ferrocenes and B(C6F5)3”, D. P. Huber, G. Kehr, K. Bergander, R. Fröhlich, G. Erker, S. Tanino, Y. Ohki, K. Tatsumi, Organometallics 2008, 27, 5279–5284.
  3. “Control of the Coordination Structure of Organometallic Palladium Complexes in an apo-Ferritin Cage”, S. Abe, J. Niemeyer, M. Abe, Y. Takezawa, T. Ueno, T. Hikage, G. Erker, Y. Watanabe, J. Am. Chem. Soc. 2008, 130, 10512–10514.
  4. “Noncovalent Insertion of Ferrocenes into the Protein Shell of apo-Ferritin”, J. Niemeyer, S. Abe, T. Hikage, T. Ueno, G. Erker, Y. Watanabe, Chem. Commun. 2008, 6519–6521.
  5. “Reinvestigation of the Bitter Compounds in Carrots (Daucus carota L.) by Using a Molecular Sensory Science Approach”, L. Schmiech, D. Uemura, T. Hofmann, J. Agric. Food Chem. 2008, 56, 10252–10260.
  6. “A New, Efficient and Direct Preparation of TITp and Related Complexes with TlBH4”, M. Kitamura, Y. Takenaka, T. Okuno, R. Holl, B. Wünsch, Eur. J. Inorg. Chem. 2008, 1188–1192.
  7. “Synthesis of 2,5-Diazabicyclo[2.2.2]octanes by Dieckmann Analogous Cyclization”, R. Holl, M. Dykstra, M. Schneiders, R. Fröhlich, M. Kitamura, E.-U. Würthwein, B. Wünsch, Aust. J. Chem. 2008, 61, 914–919.

2009

  1. “Intercalation of Stable Organic Radicals into Layered Saponite Clay”, W. L. Hemme, W. Fujita, K. Awaga, H. Eckert, Dalton Trans. 2009, 38, 7995-8004.
  2. “Intercalation of Stable Organic Radicals into Layered Inorganic Host Matrices: Prepara-tion and Structural Characterization of Cd1-xPS3(metaMPYNN)2x”, W. L. Hemme, W. Fujita, K. Awaga, H. Eckert, J. Solid State Chem. 2009, 182, 3330-3341.
  3. “Evidence for a Rapid Degenerate Hetero-Cope-type Rearrangement in Cp*W(S)2S-CH2CH=CH2”, F. Eweiner, S. Senda, K. Bergander, C. Mück-Lichtenfeld, S. Grimme, R. Fröhlich, M. Aoyama, H. Kawaguchi, Y. Ohki, T. Matsumoto, G. Kehr, K. Tatsumi, G. Erker, Chem. Asian J. 2009, 4, 1830-1833.
  4. “Catalytic hydrogenation of C=O and C=N bonds via heterolysis of H2 mediated by metal–sulfur bonds of rhodium and iridium thiolate complexes”, M. Sakamoto, Y. Ohki, G. Kehr, G. Erker, K. Tatsumi, J. Organomet. Chem. 2009, 694, 2820–2824.
  5. “Total Synthesis and Cytotoxicity Evaluation of all Ochratoxin A stereoisomers”, B. Cramer, H. Harrer, K. Nakamura, D. Uemura, H.-U. Humpf, Biorg. Med. Chem. 2010, 18, 343-347.
  6. “Palladium(II)-Catalyzed Conjugate Phosphination of Electron-Deficient Acceptors”, V. T. Trepohl, S. Mori, K. Itami, M. Oestreich, Org. Lett. 2009, 11, 1091–1094.
  7. “Azurin-poly(N-Isopropylacrylamide) Conjugates by Site Directed Mutagenesis and their Thermosensitive Behavior in Electron Transfer Processes”, N. Rosenberger, A. Studer, N. Takatani, H. Nakajima, Y. Watanabe, Angew. Chem. 2009, 48, 1946–1949.
  8. “Structure-Affinity-Relationship study of Bicyclic  Receptor Ligands”, R. Holl, C. Geiger, M. Nambo, K. Itami, D. Schepmann, B. Wünsch, Central Nervous System Agents in Medicinal Chemistry, Special Issue 2009, 9, 220–229.
  9. “Synthesis of 1,4-Diazabicyclo[3.3.1]nonan-6-ones”, D. Kracht, S. Saito, B. Wünsch, Aust. J. Chem. 2009, 62, 1684–1689.
  10. “Synthesis of a Silanol Substituted Proline Analogues as Organocatalyst”, D. Kracht, S. Saito, R. Fröhlich, B. Wünsch, Z. Naturf. 2009, 64b, 1169–1175
  11. “Fe-Catalyzed Oxidative Coupling of Heteroarenes and Methylamines”, M. Ohta, M. P. Quick, J. Yamaguchi, B. Wünsch, K. Itami, Chem. Asian J. 2009, 4, 1416–1419.
  12. “3,4-Dihydro-3H-pyrrol-2-imines as Conformationally Restrained 1,3-Diazabutadienes: Synthesis, Structural Properties and Protonation”, S. Janich, R. Fröhlich, A. Wilken, J. v. Zamory, A. Wakamiya, S. Yamaguchi, E.-U. Würthwein, Eur. J. Org. Chem. 2009, 2077–2087.
  13. “Tetraaryl-tetradecahydroporphyrazin: Novel Porphyrin Derivatives Featuring a Cyclic Benzene Ring Tetramer”, S. Janich, R. Fröhlich, A. Wakamiya, S. Yamaguchi, E.-U. Würthwein, Chem. Eur. J. 2009, 15, 10457-10463

2010

  1. “Exploring the Limits of Frustrated Lewis Pair Chemistry with Alkynes: Detection of a System that Favors 1,1-Carboboration over Cooperative 1,2-P/B-Addition”, C. Chen, F. Eweiner, B. Wibbeling, R. Fröhlich, S. Senda, Y. Ohki, K. Tatsumi, S. Grimme, G. Kehr, G. Erker, Chem. Asian J. 2010, 5, 2199-2208.
  2. “Electronic Tuning of Thiazolyl-Capped p-Conjugated Compounds via a Coordina-tion/Cyclization Protocol with B(C6F5)3”, A. Job, A. Wakamiya, G. Kehr, G. Erker, and S. Yamaguchi, Org. Lett., 2010, 12, 5470-5473 .
  3. “Aromatic C-H bond hydroxylation by P450 peroxygenases: A facile colorimetric assay for monooxygenation activities of enzymes based on the Russig’s Blue formation” O. Shoji, C. Wiese, T. Fujishiro, C. Shirataki, B. Wünsch, Y. Watanabe, J. Biol. Inorg. Chem., 2010, 15, 7, 1109-1115 .

2011

  1. “Solid state NMR strategies for the structural characterization of new hybrid materials based on the intercalation of nitroxide radicals into CdPS3”, W. L. Hemme, W. Fujita, K. Awaga, H. Eckert, Solid State Nuclear Magnetic Resonance 2011, 39, 106-115
  2. “Cooperative Catalytic Activation of Si−H Bonds by a Polar Ru−S Bond: Regioselective Low-Temperature C−H Silylation of Indoles under Neutral Conditions by a Friedel−Crafts Mechanism”, H. F. T. Klare, M. Oestreich, J. Ito, H. Nishiyama, Y. Ohki, K. Tatsumi, J. Am. Chem. Soc. 2011, 133, 3312-3315.
  3. “Incorporation of Organometallic Ru Complexes into Apo-Ferritin Cage” Y. Takezawa, P. Böckmann, N. Sugi, Z. Wang, S. Abe, T. Murakami, T. Hikage, G. Erker, Y. Watanabe, S. Kitagawa, T. Ueno, Dalton Trans. 2011, 40, 2190–2195.
  4. “Oxidative Biaryl Coupling of Thiophenes and Thiazoles with Arylboronic Acids through Palladium Catalysis: Otherwise Difficult C4-Selective C-H Arylation Enabled by Boronic Acids” Sylvia Kirchberg, Satoshi Tani, Kirika Ueda, Junichiro Yamaguchi, Armido Studer, and Kenichiro Itami, Angew. Chem. Int. Ed. 2011, 50, 2387-2391.
  5. “Synthesis of Isotopically Labeled Fusarium Mycotoxin 13C2-Moniliformin [1-Hydroxycyclobut-1-ene-3,4-dione]” Lilia Lohrey, Takeshi Murata, Daisuke Uemura, Hans-Ulrich Humpf, SYNLETT 2011, 15, 2242-2244.
  6. “Bis(phosphoryl)-Bridged Bisphenyls by Radical Phosphanylation:Synthesis and Photophysical and Electrochemical Properties” A. Bruch, A. Fukazawa, E. Yamaguchi, S. Yamaguchi, R. Fröhlich, and A. Studer, Angnew. Chem. Int. Ed., 2011, 50, 1-6.
  7. “Exploitation of an additional hydrophobic pocket of σ1 receptors: Late-stage diverse modifications of spirocyclic thiophenes by C–H bond functionalization” Christina Meyer, Benedikt Neue, Dirk Schepmann, Shuichi Yanagisawa, Junichiro Yamaguchi, Ernst-Ulrich Würthwein, Kenichiro Itami and Bernhard Wünsch, Org. Biomol. Chem., 2011, 9, 8016-8029.

2012

  1. “Preparation of Dihydroborole Derivatives by a Simple 1,1-Carboboration Route” A. Feldmann, A. Iida, R. Fröhlich, S. Yamaguchi, G. Kehr, and G. Erker, Organometallics, 31, 2445-2451 (2012).
  2. “Synthesis and Photophysical Properties of Aryl-Substituted 2-Borylbenzaldimines and Their Extended π-Conjugated Congeners” B. Neue, R. Fröhlich, B. Wibbeling, A. Fukazawa, A. Wakamiya, S. Yamaguchi, and E.-U. Würthwein, J. Org. Chem., 77, 2176-2184 (2012).
  3. “Pd-Catalyzed Direct C-H Bond Functionalization of Spirocyclic s1 Ligands: Generation of a Pharmacophore Model and Analysis of Reverse Binding Mode by Docking into a 3D Homology Model of the s1 Receptor” Christina Meyer, Dirk Schepmann, Shuichi Yanagisawa, Junichiro Yamaguchi, Valentina Dal Col, Erik Laurini, Kenichiro Itami, Sabrina Pricl, and Bernhard Wünsch, J. Med. Chem. 2012, 55, 8047-8065.
  4. “Late-Stage C-H Bond Arylation of Spirocyclic s1 Ligands for Analysis of Complementary s1 Receptor Surface” Christina Meyer, Dirk Schepmann, Shuichi Yanagisawa, Junichiro Yamaguchi, Bernhard Wünsch, and Kenichiro Itami, Eur. J. Org. Chem. 2012, 5972-5979.
  5. “Hindered Biaryls by C-H Coupling: Bisoxazoline-Pd Catalysis Leading to Enantioselective C-H Coupling” Kazuya Yamaguchi, Junichiro Yamaguchi, Armido Studer, and Kenichiro Itami, Chem. Sci. 2012, 3, 2165-2169.
  6. “Mechanistic Studies on the Pd-catalyzed Direct C-H Arylation of 2-Substituted Thiophene Derivatives with Arylpalladium Bipyridyl Complexes” Marc Steinmetz, Kirika Ueda, Stefan Grimme, Junichiro Yamaguchi, Sylvia Kirchberg, Kenichiro Itami, and Armido Studer, Chem. Asian J. 2012, 7, 1256-1260.
  7. “The 1,1-Carboboration of Bis(alkynyl)phosphines as a Route to Phosphole Framework” Juri Möbus, Quentin Bonnin, Kirika Ueda, Roland Fröhlich, Kenichiro Itami, Gerald Kehr, and Gerhard Erker, Angew. Chem. Int. Ed. 2012, 51, 1954-1957.
  8. “An Iron(II) Complex of Diamine-Bridged Bis-N-Heterocyclic Carbene” Christoph Grohmann, Takayoshi Hashimoto, Roland Froelich, Yasuhiro Ohki, Kazuyuki Tatsumi, and Frank Glorius, Organometallics, 31, 8047-8050 (2012).
  9. “Synthesis of Bis(N-heterocyclic carbene) Complexes of Iron(II) and Their Application in Hydrosilylation and Transfer Hydrogenation” Takayoshi Hashimoto, Slawomir Urban, Ryoko Hoshino, Yasuhiro Ohki, Kazuyuki Tatsumi, and Frank Glorius, Organometallics, 31, 4474-4479 (2012).
  10. “Base-Free Dehydrogenative Coupling of Enolizable Carbonyl Compounds with Silanes Involving Catalytic Generation of the Silicon Electrophile” C. David F. Koenigs, Hendrik F. T. Klare, Yasuhiro Ohki, Kazuyuki Tatsumi, and Martin Oestreich, Org. Lett., 14, 2842-2845 (2012).
  11. “Reaction of an "Invisible" Frustrated N/B Lewis Pair with Dihydrogen” Sina Schwendemann, Shunsuke Oishi, Susumu Saito, Roland Fröhlich, Gerald Kehr, and Gerhard Erker, Chem Asian J., 2012, in press. (doi: 10.1002/asia.201200776)
  12. “Double Arylation of Acetylenedicarboxylate with B(C6F5)3”, H. Nakatsuka, R. Fröhlich, M. Kitamura, G. Kehr, G. Erker, Eur. J. Inorg. Chem. 2012, 1163-1166.　
  13. “Reaction of Frustrated Lewis Pairs with Ketones and Esters”, B.-H.Xu, R. A. A. Yanez, H. Nakatsuka, M. Kitamura, R. Fröhlich, G. Kehr, G. Erker, Chem. Asian J. 2012, 7, 1347–1356.

2013

  1. “Fluorescent Modular Boron Systems Based on NNN- and ONO-Tridentate Ligands: Self-Assembly and Cell Imaging” C. Glotzbach, U. Kauscher, J. Voskuhl, N. S. Kehr, M. C. A. Stuart, R. Fröhlich, H. J. Galla, B. J. Ravoo, K. Nagura, S. Saito, S. Yamaguchi, E.-U. Würthwein, J. Org. Chem., 78, 4410-4418 (2013).
  2. “Improvement of σ1 Receptor Affinity by Late-stage C-H Bond Arylation of Spirocyclic Lactones” Christina Meyer, Benedikt Neue, Dirk Schepmann, Shuichi Yanagisawa, Junichiro Yamaguchi, Ernst-Ulrich Würthwein, Kenichiro Itami, and Bernhard Wünsch, Bioorg. Med. Chem. 2013, 21, 1844-1856.
  3. “Catalytic Generation of Borenium Ions by Cooperative B–H Bond Activation: The Elusive Direct Electrophilic Borylation of Nitrogen Heterocycles with Pinacolborane” Timo Stahl, Kristine Müther, Yasuhiro Ohki, Kazuyuki Tatsumi, Martin Oestreich, J. Am. Chem. Soc, 135, 10978-10981 (2013).
  4. “Synthesis of Thiophene-Based TAK-779 Analogues by C–H Arylation” Anna Junker, Junichiro Yamaguchi, Kenichiro Itami, and Bernhard Wünsch, J. Org. Chem. 2013, 78, 5579–5586.
  5. “Modification and Unexpected reactivity of 2-Borylbenzaldimines – Aclated and Silylated Derivatives as well as Dimeric Compounds” B. Neue, A. Wakamiya, R. Fröhlich, BWibbeling, S. Yamaguchi, E-U. Würthwein, J. Org. Chem., 2013, 78, 11747-11755
  6. “Dibenzopentalenes by B(C6F5)3 Induced Cyclization Reaction of 1,2-Bis(phenylethynyl)benzenes” C. Chen, M.Harhausen, R. Liedtke, K. Bussmann, A. Fukazawa, S. Yamaguchi, J. L. Petersen, C. G. Daniliuc, R. Fröhlich, G. Kehr, G. Erker, Angew. Chem. Int. Ed., 2013, 52, 5992-5996
  7. “Capacitance Effects Superimposed on Redox Processes in Molecular Cluster Batteries: A Synergic Route to High Capacity Energy Storage”, Heng Wang, Zhaoyang Zeng, Naoya Kawasaki, Hellmut Eckert, Hirofumi Yoshikawa, and Kunio Awaga※, Chem. Eur. J., 2013, 19(34), 11235-11240

2014

  1. “Selective Synthesis of [7]- and [8]Cycloparaphenylenes” Friederike Sibbel, Katsuma Matsui, Yasutomo Segawa, Armido Studer and Kenichiro Itami, Chem. Commun. 2014, 50, 954-956.
  2. “Synthesis of Dihydrobenzo[b]furans by Diastereoselective Acyloxyarylation” Kazuhiro Hata, Zhiheng He, Constantin Gabriel Daniliuc, Kenichiro Itami, and Armido Studer, Chem. Commun., 2014, 50, 463-465.
  3. “Diverse Modification of the 4-Methylphenyl Moiety of TAK-779 by Late-Stage Suzuki-Miyaura Cross-Coupling” Anna Junker, Dirk Schepmann, Junichiro Ya-maguchi, Kenichiro Itami, Andreas Faust, Klaus Kopka, Stefan Wagner, Bernhard Wünsch, Org. Biomol. Chem. 2014, 12, 177-186.
  4. “GluN2B-Selective N-Methyl-d-aspartate (NMDA) Receptor Antagonists Derived from 3-Benzazepines: Synthesis and Pharmacological Evaluation of Benzo[7]annulen-7-amines” Andre Benner, Alessandro Bonifazi, Chikako Shirataki, Louisa Temme, Dirk Schepmann, Wilma Quaglia, Osami Shoji, Yoshihito Watanabe, Constantin Daniliuc and Bernhard Wünsch, ChemMedChem. 2014, 9, 741–751.
  5. “The B(C6F5)3 Boron Lewis Acid Route to Arene-Annulated Pentalenes” Chao Chen, Marcel Harhausen, Aiko Fukazawa, Shigehiro Yamaguchi, Roland Frohlich, Constantin G. Daniliuc, Jeffrey L. Petersen, Gerald Kehr, Gerhard Erker, Chem. Asian J. 2014, 9, 1671-1681.